The Payment methods provided by Mollie always settle payments automatically, even if your Shopify store is set to manual capture.
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Ensure that you have the Shopify owner role↗.
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Ensure that you have the Mollie owner role.
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Select a relevant payment method activation link:
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Click Add app.
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If necessary, log in to your Shopify store.
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On your admin home page, click Install app.
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Click Connect via Mollie.
You may need to log in to your Mollie account.
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Select a Mollie website profile id from the drop-down menu.
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Click Select profile.
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Click Activate Mollie - [payment method name].